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Synergy Between Dynamics and Reactivity at Clusters and Surfaces

Louis J. Farrugia
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      The analogy between the chemistry of molecular transition metal clusters and the processes of chemisorption and catalysis at metal surfaces (the Cluster Surface analogy) has for a number of years provided an interplay between experimental and theoretical inorganic and physical chemists. This collaborative approach has borne fruit in the use of well-defined modes of metal-ligand bonding in discrete molecular clusters, models for metal-ligand binding on surfaces. Some of the key topics discussed in this book are: mechanisms of the fluxional behaviour in clusters in the liquid phase and the connections with diffusion processes on extended surfaces, and the role of metal-metal bond breaking in diffusion; analogies in the structure of chemisorbed species and related ligands on metallic clusters; analogies between benzene surface chemistry on extended metal surfaces and on metal surfaces in molecular cluster compounds with particular reference to structural distortions; and the role of mobile precursors for dissociation of chemisorption on extended metals and on clusters.
      Format: CONTRIBUTORS: Louis J. Farrugia EAN: 9780792335221 COUNTRY: United States PAGES: WEIGHT: 0 g HEIGHT: 230 cm
      PUBLISHED BY: Kluwer Academic Publishers DATE PUBLISHED: 1995-05-31 CITY: GENRE: SCIENCE / Chemistry / Inorganic, SCIENCE / Chemistry / Physical & Theoretical WIDTH: 0 cm SPINE:

      Book Themes:

      Inorganic chemistry, Organometallic chemistry

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      The analogy between the chemistry of molecular transition metal clusters and the processes of chemisorption and catalysis at metal surfaces (the Cluster Surface analogy) has for a number of years provided an interplay between experimental and theoretical inorganic and physical chemists. This collaborative approach has borne fruit in the use of well-defined modes of metal-ligand bonding in discrete molecular clusters, models for metal-ligand binding on surfaces. Some of the key topics discussed in this book are: mechanisms of the fluxional behaviour in clusters in the liquid phase and the connections with diffusion processes on extended surfaces, and the role of metal-metal bond breaking in diffusion; analogies in the structure of chemisorbed species and related ligands on metallic clusters; analogies between benzene surface chemistry on extended metal surfaces and on metal surfaces in molecular cluster compounds with particular reference to structural distortions; and the role of mobile precursors for dissociation of chemisorption on extended metals and on clusters.
      Format: CONTRIBUTORS: Louis J. Farrugia EAN: 9780792335221 COUNTRY: United States PAGES: WEIGHT: 0 g HEIGHT: 230 cm
      PUBLISHED BY: Kluwer Academic Publishers DATE PUBLISHED: 1995-05-31 CITY: GENRE: SCIENCE / Chemistry / Inorganic, SCIENCE / Chemistry / Physical & Theoretical WIDTH: 0 cm SPINE:

      Book Themes:

      Inorganic chemistry, Organometallic chemistry

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      Be the first to write a review
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